Communications - Scientific Letters of the University of Zilina 2020, 22(1):55-61 | DOI: 10.26552/com.C.2020.1.55-61

Effect of Phosphating Temperature on Surface Properties of Manganese Phosphate Coating on HSLA Steel

Jana Pastorkova1, Martina Jackova1, Filip Pastorek1, Zuzana Florkova1, Juliana Drabikova1
1 University of Zilina, Slovakia

A phosphating process modified for a high-strength low-alloy (HSLA) steel was performed at various temperatures and influence on the surface properties of the Domex steel covered by manganese phosphate (MnP) was investigated by electrochemical corrosion tests supported by a photo documentation performed by the SEM. Corrosion measurements were performed in 0.1M NaCl solution at 22±2 °C using electrochemical impedance spectroscopy and potentio-dynamic polarisation in order to obtain thermodynamic and kinetic corrosion characteristics and individual elements of equivalent circuits. It is that a temperature of the phosphating process has a very significant effect on protection properties of the created manganese phosphate coating on the Domex steel and needs to be strictly monitored. According to results of corrosion testing and surface morphology observations, the optimal temperature for the phosphating process on the tested Domex steel was chosen.

Keywords: HSLA steel; corrosion properties; manganese phosphate; surface treatment

Received: October 10, 2019; Accepted: November 4, 2019; Published: January 2, 2020  Show citation

ACS AIP APA ASA Harvard Chicago Chicago Notes IEEE ISO690 MLA NLM Turabian Vancouver
Pastorkova, J., Jackova, M., Pastorek, F., Florkova, Z., & Drabikova, J. (2020). Effect of Phosphating Temperature on Surface Properties of Manganese Phosphate Coating on HSLA Steel. Communications - Scientific Letters of the University of Zilina, 22(1), 55-61. doi: 10.26552/com.C.2020.1.55-61
Share...
Download citation
  • BibTeX (.bib)
  • Bookends (.ris)
  • EasyBib (.ris)
  • EndNote (.enw)
  • EndNote 8 (.xml)
  • ISI WoS (.isi)
  • Medlars (.medlars)
  • Mendeley (.ris)
  • MODS (.xml)
  • Papers (.ris)
  • RefWorks (.txt)
  • RefManager (.ris)
  • RIS (.ris)
  • MS Word (.xml)
  • Zotero (.ris)
    • Open full article

    References

    1. GARCIA, C. I. Chapter 6 - High strength low alloyed (HSLA) steels. In: Automotive steels. Design, metallurgy, processing and applications. University of Pittsburgh:Woodhead Publishing, 2016, p. 145-167. ISBN 0081006535
    2. LI, J., WU, J., WANG, Z., ZHANG, S., WU, X., HUANG, Y., LI, X. The effect of nanosized NbC precipitates on electrochemical corrosion behavior of high-strength low-alloy steel in 3.5 % NaCl solution. International Journal of Hydrogen Energy [online]. 2017, 42(34), p. 22175-22184 [accessed 2019-10-09]. ISSN 0360-3199. Available from: https://doi.org/10.1016/j.ijhydene.2017.03.087 Go to original source...
    3. KIM, W.K., KOH, S. U., YANG, B. Y., KIM, K. Y. Effect of environmental and metallurgical factors on hydrogen induced cracking of HSLA steels. Corrosion Science [online]. 2008, 50, p. 3336-3342 [accessed 2019-10-09]. ISSN 0010-938X. Available from: https://doi.org/10.1016/j.corsci.2008.09.030 Go to original source...
    4. PASTOREK, F., BORKO, K., DUNDEKOVA, S., FINTOVA, S., HADZIMA, B. Elektrochemicke korozne charakteristiky fosfatovanej ocele S355J2 v prostredi siranov / Electrochemical corrosion characteristics of phosphated S355J2 steel in sulfate environment (in Slovak). Koroze a ochrana materialu[online]. 2016, 60(4), p. 107-113. [accessed 2019-10-09]. ISSN 1804-1213. Available from: https://www.degruyter.com/downloadpdf/j/kom.2016.60.issue-4/kom-2016-0017/kom-2016-0017.pdf
    5. PASTOREK, F., BORKO, K., FINTOVA, S., KAJANEK, D., HADZIMA, B. Effect of surface pre-treatment on quality and electrochemical corrosion properties of manganese phosphate on S355J2 HSLA steel. Coatings [online]. 2016, 6(4), p. 46. [accessed 2019-10-09]. ISSN 2079-6412. Available from: https://doi.org/10.3390/coatings6040046 Go to original source...
    6. OLSOVSKY, M. Zaklady povrchovej upravy kovov / Basics of surface treatment of metals (in Slovak). Novaky: MSM Martin, 2015. ISBN 978-80-971929-9-0.
    7. GALVAN-REYES, C. SALINAS-RODRIGUEZ, A. FUENTES-ACEITUNO, J. C. Degradation and crystalline reorganization of hureaulite crystals during the manganese phosphating of a high strength steel. Surface and Coatings Technology [online]. 2015, 275, p. 10-20. [accessed 2019-10-09]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2015.05.030 Go to original source...
    8. KELLY, R. G., SCULLY, J. R., SHOESMITH, D., BUCHHEIT, R. G. Electrochemical techniques in corrosion science and engineering. Boca Raton, USA: CRC Press, 2003. ISBN 978-0-8247-9917-5.
    9. NARAYANAN, T. S. N. Surface pretreatment by phosphate conversion coatings - a review. Reviews on Advanced Materials Science [online]. 2005, 9(2), p. 130-177. [accessed 2019-10-09]. ISSN 1605-8127. Available from: http://www.ipme.ru/e-journals/RAMS/no_2905/narayanan.pdf
    10. WANG, C. M., LIAU, H. C., TSAI, W. T. Effects of temperature and applied potential on the microstructure and electrochemical behavior of manganese phosphate coating. Surface and coatings Technology [online]. 2006, 201(6), p. 2994-3001. [accessed 2019-10-09]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2006.06.010 Go to original source...
    11. HIVART, P., HAUW, B., BRICOUT, J. P., OUDIN, J. Seizure behaviour of manganese phosphate coatings according to the process conditions. Tribology International [online]. 1997, 30(8), p. 561-570. [accessed 2019-10-09]. ISSN 0301-679X. Available from: https://doi.org/10.1016/S0301-679X(97)00019-4 Go to original source...
    12. GALVAN-REYES, C. FUENTES-ACEITUNO, J. C. SALINAS-RODRIGUEZ, A. The role of alkalizing agent on the manganese phosphating of a high strength steel part 2: The combined effect of NaOH and the amino group (NH4OH, mono-ethanolamine and NH4NO3) on the degradation stage of the phosphating mechanism. Surface and Coatings Technology [online]. 2016, 299, p. 113-122. [accessed 2019-10-09]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2016.04.059 Go to original source...
    13. BOGI, J., MACMILLAN, R. Phosphate conversion coatings on steel. Journal of Materials Science [online]. 1997, 12(11), p. 2235-2240. [accessed 2019-10-09]. ISSN 1573-4803. Available from: https://link.springer.com/article/10.1007/BF00552245 Go to original source...
    14. KOZLOWSKI, A. Dry friction of manganese phosphate coatings on steel and cast iron. Electrodeposition and Surface Treatment [online]. 1974, 2(2), p. 109-122. [accessed 2019-10-09]. ISSN 0300-9416. Available from: https://doi.org/10.1016/0300-9416(74)90009-1 Go to original source...
    15. HADZIMA, B., PASTOREK, F., BORKO, K., FINTOVA, S., KAJANEK, D., BAGHERIFARD, S., GHOLAMI-KERMANSHAHI, M., TRSKO, L., PASTORKOVA, J., BREZINA, J. Effect of phosphating time on protection properties of hurealite coating: differences between ground and shot peened HSLA steel surface. Surface and Coatings Technology [online]. 2019, 375, p. 608-620. [accessed 2019-10-09]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2019.07.056 Go to original source...
    16. MINARIK, P., KRAL, R., HADZIMA, B. Substantially higher corrosion resistance in AE42 magnesium alloy through corrosion layer stabilization by ECAP treatment. Acta Physica Polonica-Series A General Physics [online]. 2012, 122(3), p. 614. [accessed 2019-10-09]. ISSN 1898-794X. Available from: http://psjd.icm.edu.pl/psjd/element/bwmeta1.element.bwnjournal-article-appv122z3p46kz Go to original source...
    17. BUKOVINOVA, L., HADZIMA, B. Electrochemical characteristics of magnesium alloy AZ31 in Hank's solution. Corrosion Engineering, Science and Technology [online]. 2012, 47(5), p. 352-357. [accessed 2019-10-09]. ISSN 1478-422X. Available from: https://doi.org/10.1179/1743278212Y.0000000033 Go to original source...

    This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0), which permits use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.


    Return to the content