Communications - Scientific Letters of the University of Zilina 2021, 23(2):B76-B88 | DOI: 10.26552/com.C.2021.2.B76-B88
Corrosion Behaviour of Preserved PEO Coating on AZ31 Magnesium Alloy
- 1 University of Zilina, Zilina, Slovakia
A surface treatment process, composed of plasma electrolytic oxidation (PEO) and sealing by temporary oil preservation system containing corrosion inhibitors, was performed on AZ31 magnesium alloy in order to improve its corrosion resistance in environments containing chlorides. Both atmospheric and immersion conditions were evaluated by electrochemical tests in 0.1M NaCl solution together with salt spray test according to STN EN ISO 9227 standard. The obtained results confirmed significant improvement of corrosion resistance reached by the PEO sealing in aggressive environments compared to the pure PEO coating on AZ31 surface. Hence, such a duplex coating is a very perspective alternative for magnesium alloy applications in severe conditions or for temporary protection of magnesium products coated by the PEO during marine transport.
Keywords: Plasma electrolytic oxidation; magnesium alloy; inhibitor; surface treatment; corrosion; electrochemical techniques
Received: July 17, 2020; Accepted: November 3, 2020; Prepublished online: December 16, 2020; Published: April 1, 2021 Show citation
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References
- BULING, A., ZERRER, J. Increasing the application fields of magnesium by ultraceramic®: corrosion and wear protection by plasma electrolytical oxidation (PEO) of Mg alloys. Surface and Coatings Technology [online]. 2019, 369, p. 142-155 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2019.04.025
Go to original source...
- AGHION, E., BRONFN, B., ELIEZER, D. The role of the magnesium industry in protecting the environment, Journal of Materials Processing Technology [online]. 2001, 117(3), p. 381-385 [accessed 2020-07-10]. ISSN 0924-0136. Available from: https://doi.org/10.1016/S0924-0136(01)00779-8
Go to original source...
- LAMAKA, S. V., KNORNSCHILD, G., SNIHIROVA, D. V., TARYBA, M. G., ZHELUDKEVICH, M. L., FERREIRA, M. G. S. Complex anticorrosion coating for ZK30 magnesium alloy. Electrochimica Acta [online]. 2009, 51(1), p. 131-141 [accessed 2020-07-10]. ISSN 0013-4686. Available from: https://doi.org/10.1016/j.electacta.2009.08.018
Go to original source...
- GHOLAMI-KERMANSHAHI, M., NEUBERT, V. D., TAVAKOLI, M., PASTOREK, F., SMOLA, B., NEUBERT, V. Effect of ECAP processing on corrosion behavior and mechanical properties of the ZFW MP magnesium alloy as a biodegradable implant material. Advanced Engineering Materials [online]. 2018, 20(10), 1800121 [accessed 2020-07-10]. ISSN 1527-2648. Available from: https://doi.org/10.1002/adem.201800121
Go to original source...
- GAWEL, L., NIEUZYLA, L., NAWRAT, G., DAROWICKI, K., SLEPSKI, P. Impedance monitoring of corrosion degradation of plasma electrolytic oxidation coatings (PEO) on magnesium alloy. Journal of Alloys and Compounds [online]. 2017, 722, p. 406-413 [accessed 2020-07-10]. ISSN 0925-8388. Available from: https://doi.org/10.1016/j.jallcom.2017.06.120
Go to original source...
- MOHEDANO, M., BLAWERT, C., ZHELUDKEVICH, M. L. Cerium-based sealing of PEO coated AM50 magnesium alloy. Surface and Coatings Technology [online]. 2015, 269, p. 145-154 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2015.01.003
Go to original source...
- GHALI, E., DIETZEL, W., KAINER, K. U. General and localized corrosion of magnesium alloys: a critical review. Journal of materials engineering and performance [online]. 2004, 13(1), p. 7-23 [accessed 2020-07-10]. ISSN 1059-9495. Available from: https://doi.org/10.1361/10599490417533
Go to original source...
- SONG, G. L., ATRENS, A. Corrosion mechanisms of magnesium alloys. Advanced engineering materials [online]. 2000, 1(1), p. 11-33 [accessed 2020-07-10]. ISSN 1527-2648. Available from: https://doi.org/10.1002/(SICI)1527-2648(199909)1:13.0.CO;2-N
Go to original source...
- AN, L., MA, Y., LIU, Y., SUN, L., WANG, S., WANG, Z. Effects of additives, voltage and their interactions on PEO coatings formed on magnesium alloys. Surface and Coatings Technology [online]. 2018, 354, p. 226-235 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2018.09.026
Go to original source...
- KAJANEK, D., HADZIMA, B., PASTOREK, F., NESLUSAN JACKOVA, M. Electrochemical impedance spectroscopy characterization of ZW3 magnesium alloy coated by DCPD using LASV deposition technique. Acta Metallurgica Slovaca [online]. 2017, 23(2), p. 147-154 [accessed 2020-07-10]. ISSN 1338-1156. Available from: https://doi.org/10.12776/ams.v23i2.900
Go to original source...
- ALABBASI, A., MEHJABEEN, A., KANNAN, M. B., YE, Q., BLAWERT, C. Biodegradable polymer for sealing porous PEO layer on pure magnesium: An in vitro degradation study. Applied Surface Science [online]. 2014, 301, p. 463-467 [accessed 2020-07-10]. ISSN 0169-4332. Available from: https://doi.org/10.1016/j.apsusc.2014.02.100
Go to original source...
- RAPHEAL, G., KUMAR, S., BLAWERT, C., DAHOTRE, N.B. Wear behavior of plasma electrolytic oxidation (PEO) and hybrid coatings of PEO and laser on MRI 230D magnesium alloy. Wear [online]. 2011, 271(9-10), p. 1987-1997 [accessed 2020-07-10]. ISSN 0043-1648. Available from: https://doi.org/10.1016/j.wear.2010.12.013
Go to original source...
- CASTELLANOS, A., ALTUBE, A., VEGA, J. M., GARCIA-LECINA, E., DIEZ, J. A., GRANDE, H. J. Effect of different post-treatments on the corrosion resistance and tribological properties of AZ91D magnesium alloy coated PEO. Surface and Coatings Technology [online]. 2015, 278, p. 99-107 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2015.07.017
Go to original source...
- YANG, J., BLAWERT, C., LAMAKA, S. V., SNIHIROVA, D., LU, X., DI, S., ZHELUDKEVICH, M. L. Corrosion protection properties of inhibitor containing hybrid PEO-epoxy coating on magnesium. Corrosion Science [online]. 2018, 140, p. 99-110 [accessed 2020-07-10]. ISSN 0010-938X. Available from: https://doi.org/10.1016/j.corsci.2018.06.014
Go to original source...
- CHEN, Y., LU, X., LAMAKA, S. V., JU, P., BLAWERT, C., ZHANG, T., WANG, F., ZHELUDKEVICH, M. L. Active protection of Mg alloy by composite PEO coating loaded with corrosion inhibitors. Applied Surface Science [online]. 2020, 504, p. 144462 [accessed 2020-07-10]. ISSN 0169-4332. Available from: https://doi.org/10.1016/j.apsusc.2019.144462
Go to original source...
- PASTOREK, F., HADZIMA, B., OMASTA, M., MHAEDE, M. Effect of electrodeposition temperature on corrosion resistance of calcium phosphate. Acta Metallurgica Slovaca [online]. 2014, 20(2), p. 200-208 [accessed 2020-07-10]. ISSN 1338-1156. Available from: http://dx.doi.org/10.12776/ams.v20i2.290
Go to original source...
- PASTOREK, F., HADZIMA, B., DOLEZAL, P. Electrochemical characteristics of Mg-3al-1Zn magnesium alloy surface with hydroxyapatite coating. Communications - Scientific Letters of the University of Zilina [online]. 2012, 14(4), p. 26-30 [accessed 2020-07-10]. ISSN 2585-7878. Available from: http://komunikacie.uniza.sk/index.php/communications/article/view/769
Go to original source...
- KAJANEK, D., HADZIMA, B., PASTOREK, F., NESLUSAN JACKOVA, M. Corrosion performance of AZ31 magnesium alloy treated by ultrasonic impact peening (UIP). Materials Today: Proceedings [online]. 2018, 5(13), p. 26687-26692 [accessed 2020-07-10]. ISSN 2214-7853. Available from: https://doi.org/10.1016/j.matpr.2018.08.136
Go to original source...
- HADZIMA, B., MHAEDE, M., PASTOREK, F. Electrochemical characteristics of calcium-phosphatized AZ31 magnesium alloy in 0.9 % NaCl solution. Journal of Materials Science: Materials in Medicine [online]. 2014, 25(5), p. 1227-1237 [accessed 2020-07-10]. ISSN 1573-4838. Available from: 10.1007/s10856-014-5161-0
Go to original source...
- HADZIMA, B., JANECEK, M., BUKOVINA, M., KRAL, R. Electrochemical properties of fine-grained AZ31 magnesium alloy. International Journal of Materials Research [online]. 2009, 100(9), p. 1213-1216 [accessed 2020-07-10]. ISSN 1862-5282. Available from: https://doi.org/10.3139/146.110186
Go to original source...
- KAJANEK, D., HADZIMA, B., TKACZ, J., PASTORKOVA, J., JACKOVA, M., WASSERBAUER, J. Corrosion resistance of AZ31 magnesium alloy treated by plasma electrolytic oxidation. Koroze a Ochrana Materialu [online]. 2019, 63(2), p. 65-71 [accessed 2020-07-10]. ISSN 0452-599X. Available from: DOI:10.2478/kom-2019-0008
Go to original source...
- KAJANEK, D., HADZIMA, B., BREZINA, M., JACKOVA, M. Effect of applied current density of plasma electrolytic oxidation process on corrosion resistance of AZ31 magnesium alloy. Communications - Scientific Letters of the University of Zilina [online]. 2019, 21(2), p. 32-36 [accessed 2020-07-10]. ISSN 2585-7878. Available from: https://doi.org/10.26552/com.C.2019.2.32-36
Go to original source...
- KAJANEK, D., HADZIMA, B., BUHAGIAR, J., WASSERBAUER, J., JACKOVA, M. Corrosion degradation of AZ31 magnesium alloy coated by plasma electrolytic oxidation. Transportation Research Procedia [online]. 2019, 40, p. 51-58 [accessed 2020-07-10]. ISSN 2352-1465. Available from: https://doi.org/10.1016/j.trpro.2019.07.010
Go to original source...
- CAMPOS-SILVA, I. E., RODRIGUEZ-CASTRO, G. A. Boriding to improve the mechanical properties and corrosion resistance of steels. In: Thermochemical surface engineering of steels. Woodhead Publishing, 2015, p. 651-702. ISBN 978-0-85709-592-3.
Go to original source...
- AMIRUDIN, A., THIENY, D. Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals. Progress in Organic Coatings [online]. 1995, 26(1), p. 1-28 [accessed 2020-07-10]. ISSN 0300-9440. Available from: https://doi.org/10.1016/0300-9440(95)00581-1
Go to original source...
- RIBEIRO, D. V., SOUZA, C. A. C., ABRANTES, J. C. C. Use of electrochemical impedance spectroscopy (EIS) to monitoring the corrosion of reinforced concrete. Revista IBRACON de Estruturas e Materiais [online]. 2015, 8(4), p. 529-546 [accessed 2020-07-10]. ISSN 1983-4195. Available from: https://doi.org/10.1590/S1983-41952015000400007
Go to original source...
- HADZIMA, B., PASTOREK, F., BORKO, K., FINTOVA, S., KAJANEK, D., BAGHERIFARD, S., GHOLAMI-KERMANSHAHI, M., TRSKO, L., PASTORKOVA, J., BREZINA, J. Effect of phosphating time on protection properties of hurealite coating: differences between ground and shot peened HSLA steel surface. Surface and Coatings Technology [online]. 2019, 375, p. 608-620 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2019.07.056
Go to original source...
- OLIVIER, M. G., POELMAN, M. Use of electrochemical impedance spectroscopy (EIS) for the evaluation of electrocoatings performances. In: Recent Researches in Corrosion evaluation and protection. London: IntechOpen Limited., 2012, p. 1-26. ISBN 978-953-307-920-2.
Go to original source...
- CAVALCANTI, E., FERRAZ, O., DI SARLI, A.R. The use of electrochemical impedance measurements to assess the performance of organic coating systems on naval steel. Progress in Organic Coatings [online]. 1993, 23(2), p. 185-200 [accessed 2020-07-10]. ISSN 0300-9440. Available from: https://doi.org/10.1016/0033-0655(93)80010-8
Go to original source...
- GOLABADI, M., ALIOFKHAZRAEI, M., TOORANI, M., ROUHAGHDAM, A.S. Corrosion and cathodic disbondment resistance of epoxy coating on zinc phosphate conversion coating containing Ni2+ and Co2+. Journal of Industrial and Engineering Chemistry [online]. 2017, 47, p. 154-168 [accessed 2020-07-10]. ISSN 1226-086X. Available from: https://doi.org/10.1016/j.jiec.2016.11.027
Go to original source...
- YEROKHIN, A. L., NIE, X., LEYLAND, A., MATTHEWS, A., DOWEY, S. J. Plasma electrolysis for surface engineering. Surface and Coatings Technology [online]. 1999, 122(2-3), p. 73-93 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/S0257-8972(99)00441-7
Go to original source...
- ZAID, B., MADDACHE, N., SAIDI, D., SOUAMI, N., BACHA, N., AHMED, A. S. Electrochemical evaluation of sodium metabisulfite as environmentally friendly inhibitor for corrosion of aluminum alloy 6061 in a chloride solution. Journal of Alloys and Compounds [online]. 2015, 629, p. 188-196 [accessed 2020-07-10]. ISSN 0925-8388. Available from: https://doi.org/10.1016/j.jallcom.2015.01.003
Go to original source...
- FINTOVA, S., DRABIKOVA, J., PASTOREK, F., TKACZ, J., KUBENA, I., TRSKO, L., HADZIMA, B., MINDA, J., DOLEZAL, P., WASSERBAUER, J., PTACEK, P. Improvement of electrochemical corrosion characteristics of AZ61 magnesium alloy with unconventional fluoride conversion coatings. Surface and Coatings technology [online]. 2019, 357, p. 638-650 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2018.10.038
Go to original source...
- FINTOVA, S., DRABIKOVA, J., HADZIMA, B., TRSKO, L., BREZINA, M., DOLEZAL, P., WASSERBAUER, J. Degradation of unconventional fluoride conversion coating on AZ61 magnesium alloy in SBF solution. Surface and Coatings Technology [online]. 2019, 380, p. 125012 [accessed 2020-07-10]. ISSN 0257-8972. Available from: https://doi.org/10.1016/j.surfcoat.2019.125012
Go to original source...
- LIANG, J., SRINIVASAN, P. B., BLAWERT, C., DIETZEL, W. Influence of pH on the deterioration of plasma electrolytic oxidation coated AM50 magnesium alloy in NaCl solutions. Corrosion Science [online]. 2010, 52(2), p. 540-547. [accessed 2020-10-8]. ISSN 0010-938X. Available from: https://doi.org/10.1016/j.corsci.2009.10.011
Go to original source...
- XIA, S. J., YUE, R., RATEICK JR, R. G., BIRSS, V. I. Electrochemical studies of AC/DC anodized Mg alloy in NaCl solution. Journal of The Electrochemical Society [online]. 2004, 151(3), p. 179-187 [accessed 2020-10-8]. ISSN 0013-4651. Available from: https://doi.org/10.1149/1.1646139
Go to original source...
- DARBAND, G. B., ALIOFKHAZRAEI, M., HAMGHALAM, P., VALIZADE, N. Plasma electrolytic oxidation of magnesium and its alloys: Mechanism, properties and applications. Journal of Magnesium and Alloys [online]. 2017, 5(1), p. 74-132 [accessed 2020-10-8]. ISSN 2213-9567. Available from: https://doi.org/10.1016/j.jma.2017.02.004
Go to original source...
- PASTOREK, F., HADZIMA, B., FINTOVA, S., MHAEDE, M. Influence of anodic oxidation on the polarization resistance of Ti6Al4V alloy after shot peening. Materials Science Forum [online]. 2015, 811, p. 59-62 [accessed 2020-07-10]. ISSN 1662-9752. Available from: https://doi.org/10.4028/www.scientific.net/MSF.811.59
Go to original source...
- SANKARA NARAYANAN, T. S. N. Surface pretreatment by phosphate conversion coatings. Reviews in Advanced Materials Science [online]. 2005, 9, p. 130-177 [accessed 2020-07-10]. ISSN 1338-1156. Available from: http://www.ipme.ru/e-journals/RAMS/no_2905/narayanan.pdf
- LIU, H., CAO, F., SONG, G. L., ZHENG, D., SHI, Z., DARGUSCH, M. S., ATRENS, A. Review of the atmospheric corrosion of magnesium alloys. Journal of Materials Science and Technology [online]. 2019, 35(9), p. 2003-2016 [accessed 2020-07-10]. ISSN 1005-0302. Available from: https://doi.org/10.1016/j.jmst.2019.05.001
Go to original source...
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