Communications - Scientific Letters of the University of Zilina 2024, 26(4):D109-D121 | DOI: 10.26552/com.C.2024.050
Investigating the Characteristics of Modified Bitumen with Polyphosphoric Acid Polymers and Recycled Rubber
- Department of Civil Engineering, Yazd University, Yazd, Iran
The impact of polyphosphoric acid (PPA) polymers and crumb rubber (CR) on bitumen's properties to enhance its performance was examined in this study. Laboratory samples were created with varying percentages of PPA (0.5 % to 2 %) and CR (6 % to 18 %) and subjected to extensive testing. Findings indicated that the combination of PPA and CR led to notable improvements in bitumen performance, including increased viscosity, softening point, elasticity, and recovery rates at elevated temperatures. Specifically, samples with 18 % CR and 1.0 % or 2.0 % PPA demonstrated exceptional rheological properties and strength. The optimal combination (18% CR and 1.0% PPA) resulted in a uniform structure, while the maximum CR content did not compromise bitumen integrity. Both additives effectively minimized temperature sensitivity and aging, enhancing the bitumen's performance class significantly.
Keywords: rutting resistance, modified bitumen, performance grades (PG), polyphosphoric acid polymer (PPA) waste rubber (CR) powder
Grants and funding:
We would like to thank NaftJey Oil Refinery Company for their help in carrying out the bitumen experiments for this study.
Conflicts of interest:
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Received: April 4, 2024; Accepted: July 24, 2024; Prepublished online: August 23, 2024; Published: October 1, 2024 Show citation
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References
- XU, G., YU, Y., YANG, J., WANG, T., KONG, P., CHEN, X. Rheological and aging properties of composite modified bitumen by styrene-butadiene-styrene and desulfurized crumb rubber. Polymers [online]. 2021, 13, 3037. eISSN 2073-4360. Available from: https://doi.org/10.3390/polym13183037
Go to original source...
- KUMAR, A., BERWAL, P., AL-MANSOUR, A. I., KHAN, M. A., ALAM, S., LEE, S. M., MALIK, A., IQBAL, A. Impact of crumb rubber concentration and plastic coated aggregates on the rheological performance of modified bitumen asphalt. Sustainability [online]. 2022, 14, 3907. eISSN 2071-1050. Available from: https://doi.org/10.3390/su14073907
Go to original source...
- WU, J., WANG, H., LIU, Q., GAO, Y., LIU, S. A Temperature-independent methodology for polymer bitumen modification evaluation based on DSR measurement. Polymers [online]. 2022, 14(5), 848. eISSN 2073-4360. Available from: https://doi.org/10.3390/polym14050848
Go to original source...
- PADHAN, R. K., GUPTA, A. A. Preparation, and evaluation of waste PET derived polyurethane polymer modified bitumen through in situ polymerization reaction. Construction and Building Materials [online]. 2018, 158, p. 337-345. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2017.09.147
Go to original source...
- APOSTOLIDIS, P., LIU, X., ERKENS, S., SCARPAS, A. Evaluation of epoxy modification in bitumen. Construction and Building Materials [online]. 2019, 208, p. 361-368. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2017.09.147
Go to original source...
- YANG, Q., LIU, Q., ZHONG, J., HONG, B., WANG, D., OESER, M. Rheological, and micro-structural characterization of bitumen modified with carbon nanomaterials. Construction and Building Materials [online]. 2019, 201, p. 580-589. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2018.12.173
Go to original source...
- LIN, Y., HU, C., ADHIKARI, S., WU, C., YU, M. Evaluation of waste express bag as a novel bitumen modifier. Applied Sciences [online]. 2019, 9(6), 1242. eISSN 2076-3417. Available from: https://doi.org/10.3390/app9061242
Go to original source...
- SHIRKAVAND HADAVAND, B., GHOBADI JOLA, B., DIDEHBAN, K., MIRSHOKRAIE, A. Modified bitumen emulsion by anionic polyurethane dispersion nanocomposites. Road Materials and Pavement Design [online]. 2020, 21(6), p. 1763-1774. ISSN 1468-0629, eISSN 2164-7402. Available from: https://doi.org/10.1080/14680629.2019.1567373
Go to original source...
- ABDULRAHMAN, S., HAININ, M. R., SATAR, M. K. I. M., HASSAN, N. A., AL SAFFAR, Z. H. Review on the potentials of natural rubber in bitumen modification. IOP Conference Series: Earth, and Environmental Science [online]. 2020, 476(1), 12067. ISSN 1755-1315. Available from: https://doi.org/10.1088/1755-1315/476/1/012067
Go to original source...
- AL-SABAEEI, A. M., NAPIAH, M. B., SUTANTO, M. H., ALALOUL, W. S., ZOOROB, S. E., USMAN, A. Influence of nanosilica particles on the high-temperature performance of waste denim fibre-modified bitumen. International Journal of Pavement Engineering [online]. 2022, 23(2), p. 207-220. ISSN 1029-8436, eISSN 1477-268X. Available from: https://doi.org/10.1080/10298436.2020.1737060
Go to original source...
- ANSARI, A. H., JAKARNI, F. M., MUNIANDY, R., HASSIM, S., ELAHI, Z., ZAIR, M. M. B. Mechanical performance of cup lump rubber modified asphalt mixtures incorporating polyphosphoric acid. Construction and Building Materials [online]. 2023, 408, 133625. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2019.117094
Go to original source...
- JU, Z., GE, D., LV, S., LI, Y., FAN, G., XUE, Y. Polyphosphoric acid modified soybean oil bioasphalt: rheological properties and modification mechanism. Journal of Materials in Civil Engineering [online]. 2023, 35(12), 04023441. ISSN 0899-1561, eISSN 1943-5533. Available from: https://doi.org/10.1061/JMCEE7.MTENG-15742
Go to original source...
- SCHAUR, A., UNTERBERGER, S. H., LACKNER, R. Impact of molecular structure of PP on thermo-rheological properties of polymer-modified bitumen. Construction and Building Materials [online]. 2021, 287, 122981. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2021.122981
Go to original source...
- MAHIDA, S., SHAH, Y. U., SHARMA, S. Analysis of the influence of using waste polystyrene in virgin bitumen. International Journal of Pavement Research and Technology [online]. 2021, 15(7), p. 626-639. ISSN 1996-6814, eISSN 1997-1400. Available from: https://doi.org/10.1007/s42947-021-00041-1
Go to original source...
- KAZEMI, M., GOLI, A., NASIMIFAR, M. Evaluation of the self-healing performance of polyurethane-modified bitumen using CT scan. International Journal of Pavement Research and Technology [online]. 2021, 14(2), p. 168-173. ISSN 1996-6814, eISSN 1997-1400. Available from: https://doi.org/10.1007/s42947-020-0064-6
Go to original source...
- FU, Z., TANG, Y., PENG, C., MA, F., LI, C. Properties of polymer modified asphalt by polyphosphoric acid through molecular dynamics simulation and experimental analysis. Journal of Molecular Liquids [online]. 2023, 382, 121999. ISSN 0167-7322, eISSN 1873-3166. Available from: https://doi.org/10.1016/j.molliq.2023.121999
Go to original source...
- GOKALP, I. Sustainable production of new-graded bitumen with waste styrofoam modification. Bilge International Journal of Science and Technology Research [online]. 2022, 6(1), p. 38-45. ISSN 2651-401X, eISSN 2651-4028. Available from: https://doi.org/10.30516/bilgesci.1057098
Go to original source...
- DUNKLE, M. N., PIJCKE, P., WINNIFORD, W. L., RUITENBEEK, M., BELLOS, G. Method development, and evaluation of pyrolysis oils from mixed waste plastic by GC-VUV. Journal of Chromatography A [online]. 2021, 1637, 461837. ISSN 0021-9673, eISSN 1873-3778. Available from: https://doi.org/10.1016/j.chroma.2020.461837
Go to original source...
- GLASER, R., TURNER, F., ONNEMBO, G., PLANCHE J.-P. Effect of polyphosphoric acid on bituminous binder oxidation. In: 6th Eurasphalt and Eurobitume Congress: proceedings [online]. 2016. Available from: https://doi.org/10.14311/EE.2016.320
Go to original source...
- AL-SAFFAR, Z. H., HASAN, H. G. M., ALAMRI, M., AL-ATTAR, A. A., HAMAD, A. J., ABDULMAWJOUD, A. A., ELMAGARHE, A. Assessing the effects of copolymer modifier addition on asphalt attributes: towards achieving performance optimization. Construction and Building Materials [online]. 2024, 420, 135645. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2024.135645
Go to original source...
- ASTM D6648-08. Standard test method for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). Pub. L. No. ASTM D6648-08. 2008.
- ZHOU, L., HUANG, W., XIAO, F., LV, Q. Shear adhesion evaluation of various modified asphalt binders by an innovative testing method. Construction and Building Materials [online]. 2018, 183, p. 253-263. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2018.06.064
Go to original source...
- ASTM D7552-22. Standard test method for determining the complex shear modulus (G*) of asphalt mixtures using dynamic shear rheometer [online]. Available from: https://doi.org/10.1520/D7552-22
Go to original source...
- AASHTO TP 101. Estimating damage tolerance of asphalt binders using the linear amplitude sweep. Pub. L. No. AASHTO TP 101. 2014.
- ASTM D7405. Standard test method for multiple stress creep, and recovery (MSCR) of asphalt binder using a dynamic shear rheometer. Pub. L. No. ASTM D7405. 2015.
- BALDINO, N., GABRIELE, D., LUPI, F. R., ROSSI, C. O., CAPUTO, P., FALVO, T. Rheological effects on bitumen of polyphosphoric acid (PPA) addition. Construction and Building Materials [online]. 2013, 40, p. 397-404. ISSN 0950-0618, eISSN 1879-0526. Available from: https://doi.org/10.1016/j.conbuildmat.2012.11.001
Go to original source...
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